2016
DOI: 10.3390/cryst6030024
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Inorganic–Organic Hybrid Surfactant Crystals: Structural Aspects and Functions

Abstract: Hybrid single crystals consisting of an organic surfactant and an inorganic moiety are promising functional materials. Layered crystals composed from alternate inorganic and surfactant layers are obtained by the template effect of long alkyl chain moiety. The composition, crystal packing, and molecular arrangement of the hybrid single crystals are controllable by changing the inorganic constituent and the surfactant molecular structure. The types of hybrid surfactant single crystals are twofold: (i) crystals c… Show more

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Cited by 27 publications
(22 citation statements)
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References 155 publications
(306 reference statements)
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“…POMs have been hybridized with structure-directing surfactants [14][15][16] to obtain inorganic-organic hybrid crystals [17][18][19][20][21][22][23][24][25][26][27][28][29][30][31]. The POM-surfactant hybrid crystals enable fine tuning of the structure and function by changing the combination of POM anion and surfactant cation.…”
mentioning
confidence: 99%
“…POMs have been hybridized with structure-directing surfactants [14][15][16] to obtain inorganic-organic hybrid crystals [17][18][19][20][21][22][23][24][25][26][27][28][29][30][31]. The POM-surfactant hybrid crystals enable fine tuning of the structure and function by changing the combination of POM anion and surfactant cation.…”
mentioning
confidence: 99%
“…Polyoxometalate (POM) anions are promising as the inorganic component, due to their unique redox properties, and they can be selected to design the composition and functions of hybrid layered crystals. POMs have been successfully hybridized by surfactant cations to form inorganic–organic hybrids, and single crystals …”
Section: Introductionmentioning
confidence: 51%
“…Polyoxometalates (POMs) composed of discrete early transition metal-oxide cluster anions possess many structural advantages for constructing supramolecular structures. First, POMs contain numerous exposed oxygen atoms which can act as potential hydrogen bonding interaction sites [16][17][18]. Lindqvist [Mo6O19] polyoxoanions, for example, contain three types of oxygen atoms: the exposed terminal oxygen Ot, the bridging oxygen Ob, and the central oxygen Oc.…”
Section: Introductionmentioning
confidence: 99%