Inorganic Polymeric Nanocomposites and Membranes

Guida‐Pietrasanta, F.; Boutevin, Bernard; Nuyken, Oskar; Becker, O.; Simon, George P; Dušek, Karel; Rusanov, A. L.; Likhatchev, D.; Kostoglodov, Petr V.; Müllen, Kläus; Klapper, Markus; Schmidt, M.; Usuki, Arimitsu; Hasegawa, Naoki; Katô, Makoto; Kobayashi, Shiro

doi:10.1007/978-3-540-31572-8

Cited by 4 publications

(3 citation statements)

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“…Conversion of 1 to a linear or networked polymer occurs at ambient temperature in the presence of any compound containing at least two SiAH moieties and a Pt catalyst using typical hydrosilylation chemistry. 10 In this case, either tetrakis(dimethylsiloxy)silane (TMSS) or p-dimethylsilylbenzene (DMSB; Fig. 1) were reacted with 1 in varying ratios in the presence of a platinum-cyclovinylmethylsiloxane complex in xylene to facilitate the formation of transparent polymeric material 4.…”

Section: Resultsmentioning

confidence: 99%

Transparent room temperature cured elastomers based on bisphenol A

Schear

Laskoski

2013

J. Polym. Sci. Part A: Polym. Chem.

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The synthesis of a divinyl-terminated resin from commercially available bisphenol A and polymerization with silane containing compounds utilizing a room temperature hydrosilylation reaction is demonstrated. The transparent, clear polymers exhibit excellent thermal and oxidative stability while maintaining elastomeric properties and good hardness. These polymers also have the ability to be dyed any color in the spectrum. Published 2013. † J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 523-526

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Section: Resultsmentioning

confidence: 99%

Transparent room temperature cured elastomers based on bisphenol A

Schear

Laskoski

2013

J. Polym. Sci. Part A: Polym. Chem.

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“…1,9-Decadiene was obtained from Acros. Karstedt's catalyst [Pt 2 (sym-tetramethyldivinyldisiloxane) 3 ] and Pt(PPh 3 ) 4 were purchased from Sigma Aldrich and used, respectively, as diluted solutions in hexane and dichloromethane at a concentration of 1 mg Pt/mL.…”

Section: Methodsmentioning

confidence: 99%

“…By variation of the stoichiometry of the two starting materials, the chain length and, thus, the molecular weight can be varied at will. 3 In all cases, the stoichiometry of the two starting materials was adjusted to afford intermediate oligomers bearing terminal SiAH groups. Thereafter, these oligomers were subsequently end-capped with an epoxide bearing a terminal C¼ ¼C bond to give the targeted hybrid alkylene silicone telomers bearing reactive epoxy-functional groups.…”

Section: Introductionmentioning

confidence: 99%

UV curing of epoxy functional hybrid silicones

Putzien¹,

Louis²,

Nuyken³

et al. 2012

J of Applied Polymer Sci

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Several epoxy difunctional hybrid alkylene‐silicone telomers with different silicone characters and organic spacers (linkers) were prepared via the platinum‐catalyzed polyhydrosilylation of α,ω‐dihydrosiloxanes and α,ω‐dienes. Thereafter, the resulting SiH‐terminated prepolymers were terminally functionalized with 4‐vinyl‐1,2‐epoxycyclohexane or allyl glycidyl ether. In the presence of a lipophilic cationic photoinitiator, the terminally epoxy‐functionalized hybrid alkylene–silicone telomers were photopolymerized to give crosslinked, soft, elastomeric, and transparent films. The progress of the photoinitiated cationic ring‐opening epoxide polymerizations was monitored using optical pyrometry. Potential applications for these novel photocurable epoxy‐functional telomers are as modifiers for UV curable coatings, printing inks, adhesives, and release coatings. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012

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Aromatic bisphenolA‐basedelastomers via hydrosilylation chemistry

Schear

Neal

Clarke

et al. 2020

J of Applied Polymer Sci

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The preparation of highly aromatic elastomers from a bisphenol A‐based divinyl‐terminated resin and polymerization with various aromatic silane containing compounds utilizing a room temperature hydrosilylation reaction is demonstrated. The polymers exhibit high thermal and oxidative stability with 5% weight losses around 430 and 350°C and char yields ranging from 35% to 40%. The thermosets maintained their elastomeric properties with good hardness and mechanical properties as measured by elongation measurements. The toughness of the thermosets was not improved with the inclusion of aromatic moieties but the hardness did appear to increase with the addition of more aromatic groups.

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Inorganic Polymeric Nanocomposites and Membranes

Cited by 4 publications

References 0 publications

Transparent room temperature cured elastomers based on bisphenol A

Transparent room temperature cured elastomers based on bisphenol A

UV curing of epoxy functional hybrid silicones

Aromatic bisphenolA‐basedelastomers via hydrosilylation chemistry

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