The insecticidal activity of Piper aduncum fruit has been reported, and the rice husk ash is well used as an alternative control of the new invasive pest Spodoptera frugiperda. This research aimed to determine the effectiveness of a mixture rice husk ash and P. aduncum fruit powder as an alternative control of S. frugiperda on maize. The study was conducted using a Completely Randomized Design (CRD), including preliminary and follow-up tests. The test used the sowing method on the leaf, consisting of five treatments plus control and five replications. Observation parameters were larval mortality, larval development time, percentage of pupae formed, rate of imago appearing, and sex ratio. In general, a single treatment of P. aduncum fruit powder and rice husk ash can cause the death of S. frugiperda larvae, inhibit the development of larvae that survive after treatment, and reduce the percentage of pupae and imago when compared to controls. It also affects the ratio of males and females of imago appearance. Probit analysis of the mixed treatment of P. aduncum fruit powder and rice husk ash (1:1) showed the LC50 and LC95 values were 2.06 g and 12.93 g, respectively. A mixture of rice husk ash and P. aduncum fruit powder can be used as an alternative to control S. frugiperda with the index combination value at the LC50 and LC95level were 0.58 and 0.65 respectively, which indicates the index combination is a weak synergistic.