“…30 Also catalytic asymmetric transformations including chemo-, regio-and stereo-selective hydroformylation, 31 asymmetric cross-coupling, 32 enantioselective Michael addition reactions, 33 homogeneous Pt organometallic catalysts, 34 new Pd complexes for Heck catalysis, 35 the most significant recent advances in Pd and Ni catalysed reactions, 36 and processes using planar chiral ferrocenes have been surveyed. 37 The synthetic uses for palladacycles, 38 nickelacycles, 39 organocopper() alkyne species, 40 supported zirconium metallocenes, 41 and ruthenium alkylidenes, 42 as catalysts have been surveyed. In specific areas, the zirconocene dichloride-catalysed synthesis of aldimines and ketimines, 43 and regiospecific titanocene dichloride catalysed alkylation have been reviewed.…”