Laser-induced fluorescence (LIF) measurements of singly-charged xenon ion velocities in Hall thrusters typically target metastable states due to lack of available laser technology for exciting the ground state. The measured velocity distribution of these metastable ions are assumed to reflect the ground state ion behavior. However, this assumption has not been experimentally verified. To investigate the accuracy of this assumption, a recently developed xenon ion (Xe II) collisional-radiative (CR) model is combined with a 1D fluid model for ions, using plasma parameters from higher fidelity simulations of each thruster, to calculate the metastable and ground state ion velocities as a function of position along the channel centerline. For the HERMeS and SPT-100 thruster channel centerlines, differences up to 0.2 km/s were observed between the metastable and ground state ion velocities. While both the ground state ions and metastable state ions experience the same acceleration by the electric field, these small velocity differences arise because ionization directly into these states from the slower neutral ground state can reduce their mean velocities by different amounts. Therefore, the velocity discrepancy may be larger for thrusters with lower propellant utilization efficiency and higher neutral density. For example, differences up to 1.5 km/s were calculated on the HET-P70 thruster channel centerline. Note that although the creation of slow ions can influence the mean velocity, the most probable velocity should be unaffected by these processes.