Insights into oxidovanadium (3,4,5-trimethoxyphenyl) porphyrin: A comprehensive study of synthesis, crystal structure, Hirshfeld surface analysis and computational studies

Muzaddadi, Ijaz Ullah; Murugan, Arumugam; Hemamalini, Madhukar; Tahir, Muhammed Nawaz; Saha, Shankhadeep; Bezbaruah, Bipul; Hussain, Mohammad Farid; Mandal, Vijay Kumar; Ahmed, Benzir

doi:10.1016/j.molstruc.2024.138764

Journal of Molecular Structure

2024

DOI: 10.1016/j.molstruc.2024.138764

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Insights into oxidovanadium (3,4,5-trimethoxyphenyl) porphyrin: A comprehensive study of synthesis, crystal structure, Hirshfeld surface analysis and computational studies

Ijaz Ullah Muzaddadi,

Arumugam Murugan,

Madhukar Hemamalini

et al.

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Availability of π–Cation Radical in the Oxidative Products of Oxidovanadium Porphyrin: Significance for DNA Binding and Antibacterial Activity

Muzaddadi,

Murugan,

Saha

et al. 2024

Applied Organom Chemis

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Oxidovanadium meso‐tetrakis(3,4,5‐trimethoxyphenyl) porphyrin [VO(T(OMe)3PP)] (Complex 1) was prepared. The oxidation product of Complex 1 has been characterized by cyclic voltammetry (CV), UV–visible spectrophotometer, electron paramagnetic resonance (EPR) and nuclear magnetic resonance (NMR) by the addition of SbCl5 to Complex 1. There is a one‐electron oxidation product in Complex 1 that creates π–cation radicals in CV data. This is supported by an IR spectrophotometer. Subsequent EPR spectra verified the initiation of the π–cation monoradical, which subsequently transforms into a triplet state where S = 1. DNA binding and antibacterial analysis with Complex 1 have also been analysed. In the DNA‐binding analysis, the CV data confirm the interaction between Complex 1 and DNA. Furthermore, the fact that Complex 1 is more effective at killing bacteria shows that the metal ion's chelation with the porphyrin ligand makes it more lipophilic.

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Availability of π–Cation Radical in the Oxidative Products of Oxidovanadium Porphyrin: Significance for DNA Binding and Antibacterial Activity

Muzaddadi,

Murugan,

Saha

et al. 2024

Applied Organom Chemis

View full text Add to dashboard Cite

show abstract

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Insights into oxidovanadium (3,4,5-trimethoxyphenyl) porphyrin: A comprehensive study of synthesis, crystal structure, Hirshfeld surface analysis and computational studies

Cited by 1 publication

References 58 publications

Availability of π–Cation Radical in the Oxidative Products of Oxidovanadium Porphyrin: Significance for DNA Binding and Antibacterial Activity

Availability of π–Cation Radical in the Oxidative Products of Oxidovanadium Porphyrin: Significance for DNA Binding and Antibacterial Activity

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