Insights into MoS ₂ and its composites for dye‐sensitized solar cells

Abstract

Summary Dye‐sensitized solar cells have received immense interest in the research society since its finding in 1991 mainly because of the ease of fabrication and the resources employed are low‐cost and also be environmentally friendly. In conventional dye‐sensitized solar cells, platinum is used as a counter electrode since it offers good electrocatalytic activity toward the triiodide ion reduction and also possesses high electrical conductivity. However, the corrosive nature and scarcity of platinum are considered the limitations of platinum counter electrodes in the dye‐sensitized solar cell. To overcome this, significant research is going on to explore alternative counter electrode materials. This review focuses on MoS2 and its composites. We also discuss reports where, interestingly, MoS2 can also be applied as the photoanode in dye‐sensitized solar cells (DSSCs). Importantly, the influence of morphology on the performance of the devices is summarized. Further, in the context of counter electrodes, the importance of electrochemical investigation and electrochemical stability of the electrodes have also been discussed.

S-Scheme Boron Phosphide/MoS2 Heterostructure with Excellent Light Conversion Ability for Solar Cells and Water Splitting Photocatalysts

“…Among them, monolayer MoS 2 is particularly noteworthy. These characteristics make them be widely utilized in nano-optoelectronic devices. − However, the efficiency of photoconversion and the activity of photocatalysis for individual 2D materials are suppressed by the challenge of effectively separating photogenerated electron–hole pairs (PEHPs) in space. Furthermore, the carrier mobility of the MoS 2 monolayer is relatively low, approximately 200 cm 2 V –1 s –1 , in contrast to other 2D materials like black phosphorus with a mobility of around 1000 cm 2 V –1 s –1 and boron phosphide (BP) with a mobility of approximately 10,000 cm 2 V –1 s –1 , which may significantly limit its practical applications in solar cells and water splitting photocatalysts.…”