Insights into the cycling stability of manganese-based zinc-ion batteries: from energy storage mechanisms to capacity fluctuation and optimization strategies

Liao, Yanxin; Yang, Chun; Bai, Jie; He, Qingqing; Wang, Huayu; Chen, Haichao; Zhang, Qichun; Chen, Lingyun

doi:10.1039/d4sc00510d

Chem. Sci.

2024

DOI: 10.1039/d4sc00510d

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Insights into the cycling stability of manganese-based zinc-ion batteries: from energy storage mechanisms to capacity fluctuation and optimization strategies

Yanxin Liao,

Chun Yang,

Jie Bai

et al.

Abstract: Manganese-based materials are considered as one of the most promising cathodes in zinc-ion batteries (ZIBs) for large-scale energy storage applications due to their cost-effectiveness, natural availability, low toxicity, multivalence, high...

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Cited by 14 publications

(1 citation statement)

References 223 publications

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“…In order to realize the practical application of AZIBs, the ideal AZIB cathode material is an indispensable part. [3][4][5][6] So far, the cathode materials that have been studied in depth mainly fall into the following categories: various manganese-based oxides, Prussian blue analogs (PBAs), 7 layered transition metal disulfide compounds, and vanadium-based materials. [8][9][10][11][12] As an important member of the vanadium oxide family, VO 2 (B) has been studied as an electrode material for zinc ion storage due to its open tunnel-like framework.…”

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Large scale and oxygen vacancy VO₂ porous thin sheets to enable high-performance zinc ion storage

He,

Liao,

Xue

et al. 2024

Chem. Commun.

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confidence: 99%

Large scale and oxygen vacancy VO₂ porous thin sheets to enable high-performance zinc ion storage

He,

Liao,

Xue

et al. 2024

Chem. Commun.

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Regulating the Manganese Valence State Improves the Kinetic Properties of Manganese‐Based Cathodes

Zhang,

Yuan,

Qin

et al. 2024

Adv Funct Materials

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Manganese (Mn)‐based lithium (Li)‐ion batteries with high energy density and low cost have recently attracted considerable attention. One drawback of Mn‐based batteries is the severe capacity attenuation caused by the Jahn‐Teller effect, which distorts the crystal structure and reduces the kinetics of Li‐ion insertion/extraction in the cathodes. In this study, the Mn valence state is regulated on the surface of Mn‐based oxide particles and oxygen vacancies are introduced to facilitate rapid Li‐ion transport and charge storage by adding succinonitrile (SN) to Mn‐based cathodes. Because of the reaction between SN and Mn‐based cathode particles, the contents of Mn3+ ions and oxygen vacancies increase, leading to an improvement in the Li‐ion kinetic properties of the cathodes as well as a reduction in the dissolution of Mn from the cathodes. By regulating the Mn valence state, Li‐ion and Li metal batteries with LiMn2O4 or Li‐rich Mn‐based layered oxide cathodes show significantly enhanced discharge capacity and improved cyclic performance. This study demonstrates that regulating the valence state of Mn ions is an effective strategy for enhancing the electrochemical performance of Mn‐based Li batteries and that adding SN to the cathodes is a cost‐effective method for mass production.

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Enabling Long‐cycling Aqueous Zn‐Mn₃O₄ Batteries via Segregated and Interlaced Carbon Frameworks

Pan,

Zuo,

et al. 2024

Small Methods

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Mn3O4 is a promising candidate for aqueous zinc ion batteries (ZIBs) due to its high theoretical capacity (468.5 mAh g−1) and environmental friendliness, while its practical application is hindered by slow kinetics and rapid capacity degradation. Herein, a porous Mn3O4 with segregated and interlaced carbon framework (HCF‐Mn3O4) is introduced. The in situ hydro‐assembled interlaced carbon nanotube (CNT) forms a porous structure enhancing electron conduction and accelerating Zn2+ transport; while the segregated CNT network serves as an encapsulation layer to improve mechanical stability. Together, these features facilitate the simultaneous insertion and transformation of H+/Zn2+ and enhance Zn2+ diffusion kinetics. As a result, HCF‐Mn3O4 achieves a high specific capacity of 474 mAh g−1 at 0.05 A g−1, excellent rate performance of 178 mAh g−1 at 1.50 A g−1, and stable cycling over 3000 cycles with minimal capacity decay (≈0.02% per cycle). This design offers new opportunities for developing high‐rate, long‐lasting ZIBs.

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Insights into the cycling stability of manganese-based zinc-ion batteries: from energy storage mechanisms to capacity fluctuation and optimization strategies

Abstract: Manganese-based materials are considered as one of the most promising cathodes in zinc-ion batteries (ZIBs) for large-scale energy storage applications due to their cost-effectiveness, natural availability, low toxicity, multivalence, high...

Cited by 14 publications

References 223 publications

Large scale and oxygen vacancy VO₂ porous thin sheets to enable high-performance zinc ion storage

Large scale and oxygen vacancy VO₂ porous thin sheets to enable high-performance zinc ion storage

Regulating the Manganese Valence State Improves the Kinetic Properties of Manganese‐Based Cathodes

Enabling Long‐cycling Aqueous Zn‐Mn₃O₄ Batteries via Segregated and Interlaced Carbon Frameworks

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Insights into the cycling stability of manganese-based zinc-ion batteries: from energy storage mechanisms to capacity fluctuation and optimization strategies

Abstract: Manganese-based materials are considered as one of the most promising cathodes in zinc-ion batteries (ZIBs) for large-scale energy storage applications due to their cost-effectiveness, natural availability, low toxicity, multivalence, high...

Cited by 14 publications

References 223 publications

Large scale and oxygen vacancy VO2 porous thin sheets to enable high-performance zinc ion storage

Large scale and oxygen vacancy VO2 porous thin sheets to enable high-performance zinc ion storage

Regulating the Manganese Valence State Improves the Kinetic Properties of Manganese‐Based Cathodes

Enabling Long‐cycling Aqueous Zn‐Mn3O4 Batteries via Segregated and Interlaced Carbon Frameworks

Contact Info

Product

Resources

About

Large scale and oxygen vacancy VO₂ porous thin sheets to enable high-performance zinc ion storage

Large scale and oxygen vacancy VO₂ porous thin sheets to enable high-performance zinc ion storage

Enabling Long‐cycling Aqueous Zn‐Mn₃O₄ Batteries via Segregated and Interlaced Carbon Frameworks