Insights into the origin of Co-based bimetallic catalysts with a <i>para</i>-structure exhibiting ORR and OER bifunctional activities

Zhu, Yuxi; Han, Chaoling; Chen, Zhenqian

doi:10.1039/d4qi00793j

Inorg. Chem. Front.

2024

DOI: 10.1039/d4qi00793j

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Insights into the origin of Co-based bimetallic catalysts with a para-structure exhibiting ORR and OER bifunctional activities

Yuxi Zhu,

Chaoling Han,

Zhenqian Chen

Abstract: The development of non-precious metal catalysts with oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) bifunctional activities is of great significance for the development of fuel cells. In this...

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Cited by 2 publications

References 58 publications

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Potential correlation between thermal transport and catalytic performance in single metal atom catalysts: A machine-learning interatomic potential and density functional theory study

Zhu,

Xu,

Han

et al. 2025

Surfaces and Interfaces

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Potential correlation between thermal transport and catalytic performance in single metal atom catalysts: A machine-learning interatomic potential and density functional theory study

Zhu,

Xu,

Han

et al. 2025

Surfaces and Interfaces

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Iron Porphyrin-Based Composites for Electrocatalytic Oxygen Reduction Reactions

George,

Zhao,

Wang

et al. 2024

Molecules

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The oxygen reduction reaction (ORR) is one of the most critical reactions in energy conversion systems, and it facilitates the efficient conversion of chemical energy into electrical energy, which is necessary for modern technology. Developing efficient and cost-effective catalysts for ORRs is crucial for advancing and effectively applying renewable energy technologies such as fuel cells, metal–air batteries, and electrochemical sensors. In recent years, iron porphyrin-based composites have emerged as ideal catalysts for facilitating effective ORRs due to their unique structural characteristics, abundance, advances in synthesis, and excellent catalytic properties, which mimic natural enzymatic systems. However, many articles have focused on reviewing porphyrin-based frameworks or metalloporphyrins in general, necessitating research specifically addressing iron porphyrin. This review discusses iron porphyrin as an effective catalyst in ORRs. It provides a comprehensive knowledge of the application of iron porphyrin-based composites for electrocatalytic ORRs, focusing on their properties, synthesis, structural integration with conductive supports, catalytic mechanism, and efficacy. This review also discusses the challenges of applying iron porphyrin-based composites and provides recommendations to address these challenges.

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Insights into the origin of Co-based bimetallic catalysts with a para-structure exhibiting ORR and OER bifunctional activities

Abstract: The development of non-precious metal catalysts with oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) bifunctional activities is of great significance for the development of fuel cells. In this...

Cited by 2 publications

References 58 publications

Potential correlation between thermal transport and catalytic performance in single metal atom catalysts: A machine-learning interatomic potential and density functional theory study

Potential correlation between thermal transport and catalytic performance in single metal atom catalysts: A machine-learning interatomic potential and density functional theory study

Iron Porphyrin-Based Composites for Electrocatalytic Oxygen Reduction Reactions

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