Ugidos, J.M., Barba, P., Valladares, M.I., Suarez, M., and Ellam, R.M. (2016) The Ediacaran-Cambrian transition in the Cantabrian Zone 1 (North Spain): sub-Cambrian weathering, K-metasomatism and provenance of detrital series. Journal of the Geological Society, 173(4), pp. 603-615. (doi:10.1144/jgs2016-004) This is the author's final accepted version.There may be differences between this version and the published version. You are advised to consult the publisher's version if you wish to cite from it.http://eprints.gla.ac.uk/115950/ Abstract: The Upper Ediacaran detrital succession in the Cantabrian Zone shows 9 geochemical and mineralogical changes resulting from sub-Cambrian weathering during 10 the Late Ediacaran worldwide sea-level fall. Relative to the unaltered rocks the altered 11 ones show crosscutting rubefaction of varying thickness a remarkable increase in illite, 12 K 2 O, Rb and Cs indicating K-metasomatism, and also depletion in MgO, CaO, Na 2 O, 13Be and Sr, but not in Zr, Nb, Y, Sc. The basal Cambrian siliciclastic rocks mostly 14 consist of detritus derived from the Ediacaran materials, as demonstrated by the 15 geochemical and Nd-isotope data [ Nd (t) ranges: -3.4 to -2.1, and -3.6 to -1.8, 16respectively)]. However, these geochemical features of the basal Cambrian change 17 upwards to more evolved compositions with lower Nd (t) values (-4.9 to -5.8 Worldwide, the Ediacaran-Cambrian boundary corresponds to a major unconformity in 27 most sections, suggesting a possible eustatic fall in sea level (Bartley et al. 1998; Saylor 28 2003;Knoll et al. 2004;Pyle et al. 2004 Thomas et al. 2004;Soulaimani et al. 2004; 42 Álvaro et al. 2010). 43In the Cantabrian Zone (Fig. 1) which is an angular unconformity. In the Central Iberian Zone (Fig. 1A) in slope and base-of-slope environments (Valladares et al. 2000). 97The Herrería group (Fig. 2) predominantly consists of sandstones with some levels of 98 conglomerates, shales and carbonates, with a thickness varying between 900 m in 99Barrios de Luna (Fig. 1B) and 1500 m in the Cangas de Narcea-Mieldes areas (Comte 100 1959). The lower part of this group consists of conglomerates that locally displays 101 volcanic clasts, and have a lenticular geometry (Fig. 1B) followed by Rusophycus and Cruziana species, indicating that this member yielded 106 associations of ichnofossils suggestive of a Late Corduban age (Liñan et al. 2002). 107The Lower Cambrian begins with conglomerate and sandstone-shale alternations 108 deposited in alluvial and braided-channel environments at the base, which evolved 109 upwards to tidal environments. In a restricted area close to Mieldes (Fig. 1B) other Ediacaran outcrops are observable. In the IR and Sierra de la Demanda (Fig. 1A, 126 SD), the basal Lower Cambrian also has conglomerate beds but no volcanic clasts have 127 5 been reported; instead, subrounded clasts of white quartz prevail (Álvaro et al. 2008; 128 Ábalos et al. 2011). 129
Mineralogy 130XRD semi-quantitative data on the rock-forming minerals in the ru...