Starch content serves as a crucial indicator of the quality and palatability of potato tubers. It has become a common practice to evaluate the polysaccharide content directly in tubers freshly harvested from the field. This study aims to develop models that can predict starch content prior to the harvesting of potato tubers. Very early potato varieties were cultivated in the northern and northwestern regions of Poland. The research involved constructing multiple linear regression (MLR) and artificial neural network (ANN-MLP) models, drawing on data from eight years of field trials. The independent variables included factors such as sunshine duration, average daily air temperatures, precipitation, soil nutrient levels, and phytophenological data. The NSM demonstrated a higher accuracy in predicting the dependent variable compared to the RSM, with MAPE errors of 7.258% and 9.825%, respectively. This study confirms that artificial neural networks are an effective tool for predicting starch content in very early potato varieties, making them valuable for monitoring potato quality.