“…1 However, industry interest in alternate thin film high-κ dielectrics continued due to ever increasing capacitance density requirements. Many alternative high-κ insulators have been studied including Al 2 O 3 , 452,453 AlTiO 3 (ATO), [454][455] (Ba,Sr)TiO 3 (BST), [456][457][458][459] BiTaO, 460 (Bi,Ti)SiO 3 (BTSO), 461 HfO 2 , 462 HfSiO, 463 La 2 O 3 , 464 Sm 2 O 3 , 465 SrTiO 3 (STO), 457,[466][467][468][469] Ta 2 O 5 , 470,471 TiO 2 , 455,472 Y 2 O 3 , 473,474 and ZrO 2 . [475][476][477] The International Technology Roadmap for Semiconductors (ITRS) 2026 projections for MIM capacitors indicate a need for low equivalent oxide thickness (EOT) values near 1 nm while maintaining low leakage currents of 10 −8 A/cm 2 .…”