Oxidation of bisphenol-A (BPA) was investigated using a sonophoto Fenton-like hybrid process under visible light irradiation in the presence of iron-containing perovskite LaFeO 3 catalysts. For this purpose, firstly the perovskite catalyst (LaFeO 3) was prepared by the sol-gel method and calcined at different temperatures (500, 700, and 800 • C). The prepared catalysts were characterized using XRD, SEM, FTIR, nitrogen adsorption, UV-vis DRS, and ICP/OES measurements. Among the prepared catalysts the catalyst that was calcined at 500 • C showed better catalytic activity with respect to degradation and chemical oxygen demand (COD) reduction (of 21.8% and 11.2%, respectively, after 3 h of reaction duration) than the other catalysts calcined at 700 • C and 800 • C. The catalytic activity of the LaFeO 3 perovskite catalyst calcined at 500 • C was compared with that of a TiO 2 photocatalyst containing Fe and prepared by the sol-gel method. Better photocatalytic activity in terms of degradation of BPA, total organic carbon (TOC), and COD reductions was observed with the LaFeO 3 perovskite catalyst under visible light. The degradation, COD, and TOC reductions after 6 h of oxidation were 34.8%, 26.9%, and 8.8% for the LaFeO 3 perovskite catalyst, and 33.1%, 19.7%, and 4.9% for the Fe/TiO 2 catalyst, respectively.