Quartz is an important mineral element and the most abundant rock-forming mineral that controls the mineralogy of a reservoir. At the surface, quartz is more stable than most other rock minerals because it is made up of interlocking silica that makes it quite resistant to mechanical weathering. Quartz abundance is an indication of mineralization in many metal deposits; therefore, identification and mapping of quartz in rocks are of great value for exploration and resource potential assessments. In this study, thermal infrared (TIR) bands of the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) imagery were used to identify quartz contained rocks in Gua Musang. First, the image was corrected for atmospheric effect and the study area subset for further processing. Thereafter, spectral transformation (principal component analysis (PCA)) was implemented on the TIR bands and the resulting principal component (PC) images were analysed. The three optimal PCs were selected using the strength of spectral interaction and the eigenvalues of each band. To discriminate between quartz-rich and quartz-poor rocks, RGB false colour composite and greyscale image of one of the PCs were analysed. The result shows that volcanogenic igneous rock and carbonate sedimentary rocks of Permian formation are quartz-poor while Triassic sedimentary rock made up of organic particles and sandstone is quartz-rich. On the contrary, the quartz content in the metamorphic rock varies across the area but is richer in quartz content than the igneous and carbonate rocks. Classification of the composite image classified using maximum likelihood (ML) supervised classification method produced overall accuracy and Kappa coefficient of 96.53%, and 0.95, respectively.