Electrical resistivity, chemical shrinkage and autogenous shrinkage were measured for cement pastes with different water to binder (w/b) ratios (0 . 30, 0 . 35 and 0 . 40) and fly ash replacements of cement (0%, 30% and 50%). The electrical resistivity, chemical shrinkage and autogenous shrinkage of the pastes decreased with increasing w/b ratio and fly ash content after final setting. The autogenous shrinkage development over time could be divided into a setting period, a rapid growth period, an expansion period and a slow growth period. Based on the test results, the chemical shrinkage and the autogenous shrinkage were linearly correlated to electrical resistivity after hydration for 24 h and 30 h respectively. The linear relationships will help to expand the application of electrical resistivity measurements. The parameter ª, defined as the proportion of autogenous shrinkage to linear chemical shrinkage after the final set, decreased with time due to increasing paste stiffness. This parameter will help researchers quantitatively understand the volume proportion of autogenous shrinkage and empty cavities during hydration.Notation AS(t ) autogenous shrinkage development with time (10 À6 mm/mm) CS(t ) linear chemical shrinkage development with time (10 À6 mm/mm) CS set linear chemical shrinkage before final setting time (10 À6 mm/mm) cs(t ) volumetric chemical shrinkage development with time (mm 3 /mm 3 ) L C loss on ignition of cement (%) L FA loss on ignition of fly ash (%) r fc comprehensive loss on ignition of fly ash cement paste (%) V AS sum volume of autogenous shrinkage (mm 3 ) V CS volume of chemical shrinkage (mm 3 ) V EC volume of empty cavities (mm 3 ) W 105 (t ) sample weight at temperature 1058C at age t (g) W 950 (t ) sample weight at temperature 9508C at age t (g) w nw weight ratio of non-evaporable water per gramme of anhydrous binder materials (%) â fly ash replacement of cement (%) ª proportion of autogenous shrinkage to linear chemical shrinkage after final set AS autogenous shrinkage beginning from final set (10 À6 mm/mm)˜C S linear chemical shrinkage change beginning from final set (10 À6 mm/mm) r electrical resistivity (Ùm)
IntroductionSelf-desiccation is a common phenomenon resulting from hydration in high-performance cementitious materials characterised with a low water to cementitious materials ratio. The selfdesiccation of paste in concrete normally leads to a drop in its internal relative humidity; this therefore results in autogenous shrinkage, which increases the risk of cracking in concrete structures especially at early ages (Kim and Lee, 1999;Persson, 1997). In the past decade, it has been frequently reported that early age cracking in concrete deteriorates the durability of concrete structures (Kompen, 1994;Whiting et al., 2000). Figure 1 illustrates autogenous shrinkage caused by self-desiccation. It can be seen that hydration causes the formation of empty cavities and a decrease in internal relative humidity, which creates capillary depression leading to the apparent volume ...