This research investigated different nonlinear models, state estimation techniques and control strategies applied to rechargeable Li-ion batteries and electric motors powered and adapted to these batteries. The finality of these investigations was achieved by finding the most suitable design approach for the real-time implementation of the most advanced state estimators based on intelligent neural networks and neural control strategies. For performance comparison purposes, was chosen as case study an accurate and robust EKF state of charge (SOC) estimator built on a simple second-order RC equivalent circuit model (2RC ECM) accurate enough to accomplish the main goal. An intelligent nonlinear autoregressive with exogenous input (NARX) Shallow Neural Network (SSN) estimator was developed to estimate the battery SOC, predict the terminal voltage, and map the nonlinear open circuit voltage (OCV) battery characteristic curve as a function of SOC. Focusing on nonlinear modeling and linearization techniques, such as partial state feedback linearization, for “proof concept” and simulations purposes in the case study, a third order nonlinear model for a DC motor (DCM) drive was selected. It is a valuable research support suitable to analyze the performance of state feedback linearization, system singularities, internal and zero dynamics, and solving reference tracking problems.