Recently, UWAC (underwater acoustic communication) has been studied by many scholars and researchers. DS-CDMA, OFDM (orthogonal-frequency division multiplexing), and MIMO (multi-input multi-output), modulation and error correction, and others techniques that can transmit high-speed data are used in UWAC.In this paper, we first briefly present the theoretical background of estimating the arrival time of the first non-background segment in both signals and calculate the temporal difference. We also present the initial experimental result of estimating the arrival time.