Interaction of vacuum ultraviolet excimer laser radiation with fused silica. I. Positive ion emissionThe infrared emission spectra from 0.9 to 1.651lm produced when thallium iodide vapor is photodissociated by excimer laser wavelengths of 193,248,308, and 351 nm are reported. In this spectral region, only atomic thallium transitions were observed. No emission from metastable atomic iodine at 1.3151lm (5 2 PI12 -+ 5 2 P 312 ) or thallium at 1.2831lm (6 2P3/2 -+6 2P1/ 2 ) was ever detected in contrast to strong 1.3151lm signals obtained by ultraviolet (UV) excimer laser dissociation of C 3 F71. The failure to detect metastable atomic emission from TIl photodissociation is explained by the fast quenching of the metastable states during superelastic collision with electrons produced by photoionization of the TIL Consequently, a pulsed iodine 1.3151lm laser based on photodissociation of thallium iodide does not seem practical.