for their continuous support and guidance throughout the past years. The completion of this thesis would not have been possible without the support and nurturing of them. Prof. Wang Qi Jie is always approachable even if he often has a busy schedule. He can always grasp the impact of research work and give me a clear direction. He also inspires me in how to do research and think as a researcher. He is the scientist model who I would like to become. I got to know Dr. Li Hao in a NTU career fair. It is him who led me into this wonderful ultrafast optics research field. His knowledge and passion in this field inspired me very much. He taught me not only the specified knowledge in the research field, but also the practical skills in experiment and personal developments in my life. I would not have completed this PhD journey without his support and guidance. He is both a mentor and friend to me.Dr. Zhang Ying is a mentor to me. He trained me how to be a good researcher. He taught me how to find a research problem, how to solve the problem, and how to write scientifically, with patience which cannot be underestimated. I learned so much from him. His insight and wisdom have not only guided me through this PhD program but will also inspire me in my whole life. I am extremely grateful to have such a good supervisor. I would like to extend my sincere thanks to all the staffs and students I have met in the SIMTech. I would like to thank Dr. Wang Lifeng who helped me a lot when I just joined SIMTech and taught me many things both in theory and experiment. I must also thank Dr.Li Lu who taught me many useful practical techniques in experiment. Many thanks to Dr.