A three-dimensional flower-shaped Bi2WO6 has
been prepared by a hydrothermal procedure without the addition of
an auxiliary agent and under neutral conditions with ultrapure water
serving as solvent, and the Ag2S–Bi2WO6 composite with weight ratios of 5, 10, and 15% was prepared
by a hydrothermal method. The crystallinity, morphology, mode of binding,
and optical properties of the Ag2S–Bi2WO6 composite were characterized, the results of which
showed that the composite had excellent dispersion, crystallinity,
and purity. The composite with a weight ratio of 10% had the best
photocatalytic performance, and the degradation rate of tetracycline
reached 95.51% within 120 min, an increase of 27.35% over Bi2WO6. In experiments, some focus was given to the effect
of the initial solution pH and the concentrations of humic acid and
inorganic anions on the degradation efficiency. Based on free radical
capture experiments and the semiconductor theory, the main active
substances and mechanisms in the optical catalytic reaction process
were studied, and speculation was given concerning the degradation
pathway for the target pollutants. This study has conceived novel
methods for the development of dual semiconductor systems consisting
of a Ag NP composite and in doing so has provided new approaches for
the development and photocatalysis for water pollution control.