Extreme precipitation of a minimum daily value of >30 mm often initiates natural hazards such as floods, which in turn may not only lead to property damage but also present a danger to people’s health and lives. This paper mainly focuses on examining the trends and frequency of extreme daily precipitation (EDPr) in Poland. Also, it determines natural risk zones caused by EDPr of >30 mm, >50 mm, >70 mm, and >100 mm. In Poland, a significant positive trend was found for EDPr > 30 mm, >50 mm, and >70 mm in September, and for EDPr >100 mm in May. The most frequently recorded EDPr in Poland was >30 mm, the frequency of which ranged from 0.04% in February to nearly 3% in July. EDPr of >100 mm was recorded in 4 months, from May to August. An increase in the frequency of monthly EDPr in Poland occurred mainly in the southwestern and western parts. In Poland, three hazard zones of various frequencies of EDPr events were determined. In Zone III, which is in the southwestern and southern parts of the country, EDPr events occurred far more often than in Zone I; on average, four times more in the spring–summer season and slightly more than five times more in the autumn–winter season. The obtained results may help in the building of modern management and monitoring systems for the prevention of natural hazards caused by extreme precipitation.