Interaction of benzene with water and aqueous solutions of alkali metal chlorides

Taking into Account Density Fluctuations in a Solvent in a Model of Dissolution

“…In essence, the called conclusions are obtained owing to taking into account, evidently or not evidently, effect of electric field described in ref. [9]. Hence such effect should be taken into consideration in advanced models of solubility, including computer simulation.…”

“…is caused by the molecular size decreasing because of pressing by reaction field forces [9]. It can be found from the next expression: µ with values of r δ are given in the fifth column of Table 2.…”

“…It was shown in ref. [9] that there are neither electrical nor chemical interactions between the solute and the solvent in the aqueous solution of benzene. This fact will be used below at construction the simplest version of solubility model in which density fluctuations in the solute are taken into account.…”

“…Experimental details including purification of substances, recording and measuring spectral shifts were done in refs. [9] [10] [11]. Data concerning solubilities are cited below.…”

“…Nevertheless, addition salt KCl into aqueous solution of benzene does not destroys its hydrate cell, in contrast to addition such salts as RbCl and CsCl [9] which are more actively then KCl [19]. .…”