Interaction of Cyclohexane-Methyl Acetate Binary System through Dielectric Properties at Different Temperatures

Abstract

ABSTRACT. The present paper reports the study of binary mixtures and their properties over the entire range of composition at temperatures 288, 298, 308 and 318 K. Excess dielectric constant, excess molar volume, excess refractive index, molar refraction and excess molar refraction at different temperatures have been computed from the experimentally measured values of the aforesaid parameters and fitted to the Redlich-Kister equation. Excess dielectric constant, excess molar volume excess molar polarizations are negative whereas excess refractive indices are positive over entire mole fraction of methyl acetate for all temperatures. The results are discussed in light of intermolecular interactions occurring in the binary mixture. Estimated coefficients of the Redlich-Kister polynomials and the standard error along the coefficients are also reported.

Dielectric Behavior of Binary Mixtures of 2,3-Dichloroaniline with 2-Methoxyethanol Using Microwave X-Band

“…Recently several workers [1][2][3][4][5] have reported the utility of dielectric measurement while studying the molecular interaction in a binary mixture of liquids. Rana and Vyas 6 have studied the relaxation time and distributed parameters for binary mixture of 3-bromoanline and 1-proponal and suggested the interaction between the constitute molecules.…”