Interaction of endogenic methane and sulfur: a possible initial stage of condensation conversion and abiogenic genesis of oil

Lur'e, M. A.; Шмидт, Ф. К.

doi:10.1080/17415990701670288

Cited by 4 publications

(3 citation statements)

References 20 publications

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“…The hypothesis put forward in [5][6][7] regarding the origin of the abiogenous component of crude oils, which is based on the notions about the composition of endogenous fluids, the presence in them of hydrogen, methane, elemental sulfur (S 0 ), hydrogen sulfide and other gases, and metals, vanadium and nickel in particular, the variability of the ratios of these components [8][9][10], and the reactivities of the latter, especially dehydrocondensation effect of S 0 on the hydrocarbon component with formation of all kinds of crude oil components [11], is capable of explaining the above-noted mechanisms of variation in the composition of crude oils and fractions thereof, distribution in the latter of sulfur and its compounds.…”

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confidence: 99%

Sulfur and metal contents – genetic aspects of crude oils

Lur'e

Шмидт

2009

Chem Technol Fuels Oils

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Increased sulfur content, condensation, and amount of vanadium (V > Ni) observed in real crude oil systems are explained from the standpoint of formation of abiogenous constituents of crude oil systems, which is a part of the overall process of oxidative transformations of endogenous fluids as they move toward the earth's surface and is caused by oxidative dehydrocondensation effect on the hydrocarbon component of elemental sulfur S 0 present in the fluids. These mechanisms arise from oxidation of deep-earth (plutonic) hydrogen sulfide to S 0 and SO − 2 4 due to intensification of oxidative conditions in the process of ascending movement of the fluid and acceleration of oxidative processes by vanadium present in the system.Whatever the views on the sources and ways of formation of the hydrocarbon component of crude oil systems, for an understanding of the processes that gave rise to crude oils it is essential to clarify how the observed association of elements was formed and what the reasons are for the appearance in crude oils of heteroatoms, primarily sulfur and metals (V, Ni, etc.). Are these heteroelements "sputniks" (associates) of the hydrocarbon system, which made their way into the system in varying quantities at some stage of its origin and imparted to it some specific features but not determined such important characteristics as the degree of condensation and fractional composition of the crude oil, or did they take active part in the crude oil formation process from its earliest stages and did their action bear a deterministic character?The latter is supported by a multitude of data showing stable direct correlations between concentrations of heteroelements, dominant among them being primarily S, V, and Ni, relative quantity of V (V/Ni), concentrations of aromatic and asphalt-and resin-bearing structures, and viscosity and density values [1]. Worthy of special note is the combination of high sulfur and vanadium concentrations in heavy sulfur-bearing oils, malthas (viscid bitumens), asphalts, and black shales [2].Furthermore, a direct relationship is observed between sulfur-bearing oils and their reserves in several countries and continents and within the boundaries of a single oil-bearing region (West Siberia) [3]. To this must

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mentioning

confidence: 99%

Sulfur and metal contents – genetic aspects of crude oils

Lur'e

Шмидт

2009

Chem Technol Fuels Oils

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“…Таким образом, преобразование смеси СН 4 -S 0 может сопровождаться в процессе движения глубинного флюида к поверхности Земли образованием соединений, составляющих часть нефти. В работах [30][31][32] обоснован вывод о том, что в процессе движения флюида могут происходить процессы, приводящие к образованию смеси соединений, состав которых хорошо согласуется с показателями реальных нефтей. Главным подтверждением правомерности такого вывода являются многочисленные данные о том, что с повышением сернистости нефтей увеличиваются их плотность, доли тяжелых фракций и АСК, при этом уменьшается доля газовой составляющей [30][31][32].…”

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“…В работах [30][31][32] обоснован вывод о том, что в процессе движения флюида могут происходить процессы, приводящие к образованию смеси соединений, состав которых хорошо согласуется с показателями реальных нефтей. Главным подтверждением правомерности такого вывода являются многочисленные данные о том, что с повышением сернистости нефтей увеличиваются их плотность, доли тяжелых фракций и АСК, при этом уменьшается доля газовой составляющей [30][31][32]. Характер этих изменений свидетельствует о том, что с увеличением концентрации серы во флюиде усиливается вовлеченность легкого УВ в поликонденсационные процессы, сопровождающиеся увеличением масштабов нефтезалежей [32].…”

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Oil and Gas Systems, Coal Are Components of Hydrocarbon Sphere of the Earth

Lur'e

2019

Izvestiâ vysših učebnyh zavedenij. Neftʹ i gaz

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Comparison of elemental compositions of oil, coal and biomaterial has shown that a source of oil and gas systems and coal is mainly not biomass, but the deep abiogenic hightemperature fluids representing a mixture of light hydrocarbon, sulfur, metal-containing structures, etc. In the course of the fluids movement towards the Earth’s surface, hydrocarbon under catalytic action of sulfur and metals undergoes polycondensation transformations to afford hydrocarbons of various types and molecular mass, sulfur- and organometallic compounds. Formation of a hydrocarbon system depends on a structure of the fluid.

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