Interaction of the Dihydropyridine/Pyridinium Redox Pair Fixed into a V-Shaped Conformation

Hirao, Yasukazu; Kubo, Takashi; Teraoka, Mitsuru

doi:10.3987/com-19-14163

Cited by 1 publication

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“…was attempted using literature methods. 157 However, this attempt was also failed as there was no indication of reduction of the nitro group and workup yielded the starting material.…”

Section: Synthesis Of Pyridine-based Top For Phenylacetylene Macrocyclementioning

confidence: 99%

Exploring Bodipy Dyes in Light-Harvesting, Energy Transfer and Bio-Inspired Probe Designs

Sritharan

2024

Preprint

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<p>Attempts to mimic Nature and create artificial photosynthetic systems has transformed from an active chemical curiosity to a full-blown research pursuit, owing to our need for sustainable energy generation. To this end, this thesis explores the use of the dye, BODIPY (4-4’-difluoro-4-bora-3a,4a-diaza-s-indacene). BODIPY dyes have gained considerable attention owing to their highly desirable properties, such as strong absorption, fluorescence quantum yields, good chemical and photo-stability. These desirable physiochemical properties have led to materials that can be used for chemosensors, biological labeling agents, fluorescent switches, laser dyes, and organic sensitizers. For this thesis, a pentamethylBODIPY (2.1a) derivative was further functionalized in order to examine its potential for a myriad of applications.</p> <p>Energy extraction in terms of dye-sensitized solar cells (DSSCs) requires electronically asymmetric molecules as building blocks. In Chapter 2, pentamethylBODIPY (2.1a) was modified using Schiff-base chemistry to create a family of dye building blocks. In this chapter, mono ß-substitution was used to break symmetry in this potential BODIPY building block, thus tuning the electronic and optical properties.</p>

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“…was attempted using literature methods. 157 However, this attempt was also failed as there was no indication of reduction of the nitro group and workup yielded the starting material.…”

Section: Synthesis Of Pyridine-based Top For Phenylacetylene Macrocyclementioning

confidence: 99%

Exploring Bodipy Dyes in Light-Harvesting, Energy Transfer and Bio-Inspired Probe Designs

Sritharan

2024

Preprint

View full text Add to dashboard Cite

show abstract

Interaction of the Dihydropyridine/Pyridinium Redox Pair Fixed into a V-Shaped Conformation

Cited by 1 publication

References 32 publications

Exploring Bodipy Dyes in Light-Harvesting, Energy Transfer and Bio-Inspired Probe Designs

Exploring Bodipy Dyes in Light-Harvesting, Energy Transfer and Bio-Inspired Probe Designs

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