The Al-Mo and Al-Fe-Mo systems were critically assessed using the CALPHAD technique. The solution phases (liquid, fcc and bcc) were described by a substitutional solution model. The nonstoichiometric compound AlMo 3 was described by a two-sublattice model (Al,Mo)(Al,Mo) 3 in the Al-Mo binary system and (Al,Fe,Mo)(Al,Fe,Mo) 3 in the Al-Fe-Mo ternary system. Other comin the Al-Mo system were treated as stoichiometric compounds in the binary system and as line compounds Al m (Fe,Mo) n in the Al-Fe-Mo ternary system. The compounds l and Fe 2 Mo in the Fe-Mo system were treated as (Al,Fe) 7 Fe 2 (Fe,Mo) 4 and (Fe,Mo) 2 (Al,Mo) in the Al-Fe-Mo system, respectively. ) 0.235 Al 0.6275 (Al,Va) 0.1375 in the Al-Fe-Mo system, respectively. Ternary compounds s 1 and s 2 were treated as Al 8 (Al,Fe)Mo 3 and (Al,Fe,Mo)(Va) 3 , respectively. A set of self-consistent thermodynamic parameters of the Al-Fe-Mo system was obtained.