Interaction of zinc deposited from an alkaline solution with a polycrystalline silver substrate

Hendrikx, Jlhm Jos; Visscher, Whm Wil; Barendrecht, E Embrecht

doi:10.1016/0013-4686(83)85075-0

Cited by 6 publications

(3 citation statements)

References 3 publications

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“…Briefly, the samples were treated with epoxy and cured after which they were cut in three segments, and the cross section respectively. Peak Ag aI was ascribed to ε-phase alloy AgZn 3 and peak Ag aII is to ζ-phase alloy AgZn 3 by Hendrikx et al [32]. These two alloy peaks are formed through diffusion [32].…”

Section: Methodsmentioning

confidence: 95%

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Impact of anode substrates on electrodeposited zinc over cycling in zinc-anode rechargeable alkaline batteries

Wei

Desai

Yadav

et al. 2016

Electrochimica Acta

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Electrochemical behavior of Ag, Bi, Cu, Fe, Ni and Sn substrates on zinc deposition was evaluated over battery cycling by cyclic voltammetry and electrochemical impedance spectroscopy. The effect of Bi, Cu, Ni, and Sn substrates on zinc electrodeposition during battery cycling was investigated using scanning electron microscopy and X-ray diffraction. The corrosion behavior of each metal in 9 M KOH and the corrosion rates of zinc plated on each substrate were analyzed by Tafel extrapolation method from the potentiodynamic polarization curves and electrochemical impedance spectroscopy. Although the charge-transfer resistance (R ct) of zinc electrodeposition is lowest on Sn, Sn eventually corrodes on cycling in alkaline media. Use of Ni as a substrate causes zinc to deteriorate on account of rapid hydrogen evolution. Bi and Cu substrates are more suitable for use as current collectors in zinc-anode alkaline

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Section: Methodsmentioning

confidence: 95%

“…Peak Ag aI was ascribed to ε-phase alloy AgZn 3 and peak Ag aII is to ζ-phase alloy AgZn 3 by Hendrikx et al [32]. These two alloy peaks are formed through diffusion [32]. During the cathodic sweep at 0.15 V vs. Hg|HgO peak Ag cI takes place, which is ascribed to Ag reduction reaction.…”

Section: Methodsmentioning

confidence: 96%

Impact of anode substrates on electrodeposited zinc over cycling in zinc-anode rechargeable alkaline batteries

Wei

Desai

Yadav

et al. 2016

Electrochimica Acta

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“…The identity and structure of the substrate also has a strong effect on the Zn deposit character. Investigations of Zn electrodeposition on various substrates have been carried out, including Cu, Au, Cd, Znl Pb, T1, Sn, In, Ag, carbon, and steel (461)(462)(463)(464)(465)(466)(467)(468)(469)(470)(471). Studies by McBreen et al (461)(462)(463)(464) have shown that Cu substrates produce hexagonal Zn deposits oriented parallel to the basal plane; Pb, In, and Sn substrates produce compact Zn oriented perpendicular to the basal plane; and Cd substrates produce Zn deposits of intermediate character.…”

Section: Fundamental Studiesmentioning

confidence: 99%

The Secondary Alkaline Zinc Electrode

McLarnon

Cairns

1991

J. Electrochem. Soc.

458

328

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Zinc is the most commonly used battery electrode, and zinc primary batteries have found numerous applications. The zinc electrode is electrochemically reversible in alkaline electrolytes, and there is a strong incentive to develop a practical secondary battery based on this metal. However, secondary batteries that use zinc electrodes typically exhibit short lifetimes, because of problems with zinc material redistribution and undesirable zinc morphologies that form during recharge. There has been a worldwide effort to develop a long-lived secondary alkaline zinc electrode, and marked improvements in cell lifetimes have resulted. This article reviews these efforts, paying particular attention to research and development during the period 1975-1990.

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ChemInform Abstract: INTERACTION OF ZINC DEPOSITED FROM AN ALKALINE SOLUTION WITH A POLYCRYSTALLINE SILVER SUBSTRATE

Hendrikx

Visscher

Barendrecht

1983

Chemischer Informationsdienst

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Interaction of zinc deposited from an alkaline solution with a polycrystalline silver substrate

Cited by 6 publications

References 3 publications

Impact of anode substrates on electrodeposited zinc over cycling in zinc-anode rechargeable alkaline batteries

Impact of anode substrates on electrodeposited zinc over cycling in zinc-anode rechargeable alkaline batteries

The Secondary Alkaline Zinc Electrode

ChemInform Abstract: INTERACTION OF ZINC DEPOSITED FROM AN ALKALINE SOLUTION WITH A POLYCRYSTALLINE SILVER SUBSTRATE

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