Interactions of Enantiomeric Ruthenium (II) Complexes with Polynucleotides as Studied by Circular Dichroism, Electric Dichroism Measurements, and Photolysis

Naing, Kyaw Myo; Takahashi, Masayuki; Taniguchi, Masateru; Yamagishi, Akihiko

doi:10.1021/ic00105a054

Cited by 80 publications

(48 citation statements)

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“…(Wang et al, 1996;Wall et al, 1999;Naing et al, 1995). Some Co(II)-phenanthroline complexes have been synthesized and structures were determined (Ding et al, 2006;Xuan & Zhao, 2007;Zhao et al, 2008).…”

Section: Methodsmentioning

confidence: 99%

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Aqua(dicyanamido-κN¹)(2,9-dimethyl-1,10-phenanthroline-κ²N,N′)(nitrato-κ²O,O′)cobalt(II)–2,9-dimethyl-1,10-phenanthroline–water (2/1/2)

Fenghua

Zhao

2011

Acta Cryst E

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2 O, the Co II ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand, a bidentate nitrate anion, a water molecule and a monodentate dicyanamide group in a distorted octahedral geometry. One uncoordinated dmphen molecule is situated on a crystallographic twofold axis and the asymmetric unit is completed by one water molecule. In the crystal, molecules form a onedimensional framework in the [001] direction through O-HÁ Á ÁN and O-HÁ Á ÁO hydrogen bonds. The crystal packing is further stabilized by -stacking interactions between the dmphen rings of neighboring molecules, with a centroidcentroid separation of 3.5641 (8) Å and a partially overlapped arrangement of parallel dmphen rings with a distance of 3.407 (2) Å . Related literature

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Section: Methodsmentioning

confidence: 99%

“…For background to metal-phenanthroline complexes, see: Naing et al (1995); Wang et al (1996); Wall et al (1999). For related Co(II)-phenanthroline structures, see: Ding et al (2006); Xuan & Zhao (2007); Zhao et al (2008).…”

Section: Related Literaturementioning

confidence: 99%

Aqua(dicyanamido-κN¹)(2,9-dimethyl-1,10-phenanthroline-κ²N,N′)(nitrato-κ²O,O′)cobalt(II)–2,9-dimethyl-1,10-phenanthroline–water (2/1/2)

Fenghua

Zhao

2011

Acta Cryst E

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“…For the features of metal-phenanthroline complexes, see: Naing et al (1995); Wang et al (1996); Wall et al (1999). For related structures, see : Cheng et al (2007); Xuan et al (2007); Zhao et al (2007).…”

Section: Related Literaturementioning

confidence: 99%

“…Metal-phenanthroline complexes have attracted much attention because of their peculiar features (Wang et al, 1996;Wall et al, 1999;Naing et al, 1995). Some Cu(II)-phenanthroline complexes have been synthesized and structures were determined (Cheng et al, 2007;Xuan et al, 2007;Zhao et al, 2007).…”

Section: S1 Commentmentioning

confidence: 99%

(2,9-Dimethyl-1,10-phenanthroline-κ²N,N′)bis(2-hydroxybenzoato-κO)copper(II)

2008

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Key indicators: single-crystal X-ray study; T = 291 K; mean (C-C) = 0.006 Å; R factor = 0.045; wR factor = 0.121; data-to-parameter ratio = 13.2.The Cu II atoms in the two independent molecules of the title compound, [Cu(C 7 H 5 O 3 ) 2 (C 14 H 12 N 2 )], are each coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) molecule and two monodentate 2-hydroxybenzoate anions in a distorted tetrahedral geometry. The crystal packing is stabilized by intramolecular hydrogen bonding andinteractions between the dmphen rings of neighboring molecules, with distances between their ring planes of 3.5670 (4) and 3.5181 (9) Å . Related literature

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“…[1][2] The ligands or the metal in these complexes can be varied in an easily controlled manner to facilitate an individual application, thus providing an easy access 335 for the understanding of details involved in DNAbonding and cleavage. 3 Some [Co(phen) 2 XY] n+ complexes have the DNA-binding and photochemical DNA cleavage characteristics.…”

Section: Metal Complexes Of the Type [M(ll)mentioning

confidence: 99%

Structure of Chloro bis(1,10-phenanthroline)Cobalt(II) Complex, [Co(phen)₂(Cl)(H₂O)]Cl·2H₂O

Zhao¹,

Lu²,

Jian³

2003

Journal of the Korean Chemical Society

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Interactions of Enantiomeric Ruthenium (II) Complexes with Polynucleotides as Studied by Circular Dichroism, Electric Dichroism Measurements, and Photolysis

Cited by 80 publications

References 0 publications

Aqua(dicyanamido-κN¹)(2,9-dimethyl-1,10-phenanthroline-κ²N,N′)(nitrato-κ²O,O′)cobalt(II)–2,9-dimethyl-1,10-phenanthroline–water (2/1/2)

Aqua(dicyanamido-κN¹)(2,9-dimethyl-1,10-phenanthroline-κ²N,N′)(nitrato-κ²O,O′)cobalt(II)–2,9-dimethyl-1,10-phenanthroline–water (2/1/2)

(2,9-Dimethyl-1,10-phenanthroline-κ²N,N′)bis(2-hydroxybenzoato-κO)copper(II)

Structure of Chloro bis(1,10-phenanthroline)Cobalt(II) Complex, [Co(phen)₂(Cl)(H₂O)]Cl·2H₂O

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Interactions of Enantiomeric Ruthenium (II) Complexes with Polynucleotides as Studied by Circular Dichroism, Electric Dichroism Measurements, and Photolysis

Cited by 80 publications

References 0 publications

Aqua(dicyanamido-κN1)(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)(nitrato-κ2O,O′)cobalt(II)–2,9-dimethyl-1,10-phenanthroline–water (2/1/2)

Aqua(dicyanamido-κN1)(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)(nitrato-κ2O,O′)cobalt(II)–2,9-dimethyl-1,10-phenanthroline–water (2/1/2)

(2,9-Dimethyl-1,10-phenanthroline-κ2N,N′)bis(2-hydroxybenzoato-κO)copper(II)

Structure of Chloro bis(1,10-phenanthroline)Cobalt(II) Complex, [Co(phen)2(Cl)(H2O)]Cl·2H2O

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Aqua(dicyanamido-κN¹)(2,9-dimethyl-1,10-phenanthroline-κ²N,N′)(nitrato-κ²O,O′)cobalt(II)–2,9-dimethyl-1,10-phenanthroline–water (2/1/2)

Aqua(dicyanamido-κN¹)(2,9-dimethyl-1,10-phenanthroline-κ²N,N′)(nitrato-κ²O,O′)cobalt(II)–2,9-dimethyl-1,10-phenanthroline–water (2/1/2)

(2,9-Dimethyl-1,10-phenanthroline-κ²N,N′)bis(2-hydroxybenzoato-κO)copper(II)

Structure of Chloro bis(1,10-phenanthroline)Cobalt(II) Complex, [Co(phen)₂(Cl)(H₂O)]Cl·2H₂O