Intercalated-Laurate-Enhanced Photocatalytic Activities of Ni/Cr-Layered Double Hydroxides

Abstract

Laurate (LA−)-intercalated nickel–chromium-layered double hydroxides (LDHs) were synthesized using the co-precipitation method and investigated as a potential photocatalyst for methylene orange (MO) degradation. For comparison, a series of LDHs with various molar ratios of Ni2+(or Mg2+)/Cr3+(or Fe3+)/LA−(or CO32−) were prepared. X−ray diffraction (XRD) and element analysis showed that Ni/Cr(2/1)−1.0 LA LDH had the most ordered crystal structure, and showed the same photocatalytic decolorization performance as Mg/Cr(2/1)−1.0LA LDH towards MO, which was significantly superior to Ni/Cr−CO3 LDH, Ni/Fe(2/1)−1.0LA LDH, and Ni/Cr−CO3 LDH with LA−, and Cr3+ with LA−. The photocatalytic removal rate of MO with the initial concentration of 100 mg/L by Ni/Cr(2/1)−1.0LA LDH (0.5 g/L) could be up to 80% with UV light irradiation for 3 h, which was almost twice higher than that of the sorption test. The photocatalytic reaction was in accordance with the pseudo-first-order kinetics, which implied that the catalytic process took place on the surface of the catalyst. All the results indicate the photodegradation of MO by Ni/Cr−LA LDHs was enhanced by the sorption of MO onto the intercalated LA− in the interlayer. The free radical capture experiments suggest that the main role of the photocatalytic mechanism of Ni/Cr−LA LDHs could be the •O2− with high oxidation activity produced by the electron-hole pairs of LDH, as excited by UV light. Additionally, the •O2− further reacted with the adjacent MO molecule pre-sorbed on the intercalated LA.

Hydrothermally Synthesized ZnCr- and NiCr-Layered Double Hydroxides as Hydrogen Evolution Photocatalysts

“…In addition, many LDHs have been revealed to possess band edge potentials that are suitable for hydrogen evolution and a bandgap energy E g < 3 eV, allowing them to utilize visible light [54][55][56]. Regarding the objects of this study, ZnCr-and NiCr-LDHs have already been tested in the reactions of hydrogen [57][58][59][60] and oxygen [61][62][63] generation, decomposition of organic dyes [64][65][66][67], insecticides [68] and antibiotics [69,70] as well as reduction of olefins by hydrazine [71].…”