Supercapacitors are widely used in many fields owing to their advantages, such as high power, good cycle performance, and fast charging speed. Among the many metal-oxide cathode materials reported for supercapacitors, NiMoO 4 is currently the most promising electrode material for high-specific-energy supercapacitors. We have employed a rational design approach to create a nanorodlike NiMoO 4 structure, which serves as a conductive scaffold for supercapacitors; the straightforward layout has led to outstanding results, with nanorod-shaped NiMoO 4 exhibiting a remarkable capacity of 424.8 F g −1 at 1 A g −1 and an impressive stability of 80.2% capacity preservation even after 3500 cycles, which surpasses those of the majority of previously reported NiMoO 4 materials. NiMoO 4 //AC supercapacitors demonstrate a remarkable energy density of 46.31 W h kg −1 and a power density of 0.75 kW kg −1 . This synthesis strategy provides a facile method for the fabrication of bimetallic oxide materials for high-performance supercapacitors.