Research
in miniaturization of devices is driven by the presence
of new challenges in small-sized particles. Magnetic interactions
at the heterostructure interface, specifically the interface-driven
properties such as exchange bias (EB) in core–shell magnetic
quantum dots (QDs), have become one of the primary fields of interest
in nanomagnetism research. The major deterrent in small-sized QDs
is the presence of superparamagnetic limit, responsible for low or
insignificant anisotropy in these materials. Formation of a sharp
interface at the junction of antiferromagnetic (AFM) and ferrimagnetic
(FiM) heterostructures can improve anisotropy that can overcome the
superparamagnetic limit in these small-sized QDs. Herein, we demonstrate
a two-step synthesis of CoO/CoFe2O4 core–shell
QDs and their characterization to study the effect of magnetic interaction
at the interface. Formation of highly crystalline sharp interfaces,
obtained as a result of interface modeling, results in a strong exchange
coupling at the AFM core/FiM shell interface, leading to a large EB
value (H
E = 5.6 kOe). This EB value is
comparable with the largest H
E value reported
for small-sized nanoparticles.