2009 11th Electronics Packaging Technology Conference 2009
DOI: 10.1109/eptc.2009.5416457
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Interface reaction of Pb-free Sn-3.5Ag solder with Ni-Sn-P metallization

Abstract: The electrolessly plated Ni-P has been extensively studied due to its coating uniformity, selectivity and low coating stress. However, the use of lead-free solders accelerates interfacial reaction because its higher melting points and higher Sn content than the conventional Pb-Sn solders. In this work, we developed a ternary electroless Ni-Sn-P (7~8 wt.% of P and 1.4 wt.% of Sn) alloy to be used as the soldering metallization. Besides having good solderability, the presence of Sn in electroless Ni-Sn-P changes… Show more

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“…In solid-state reactions, the morphology of Ni3Sn4 becomes quite different as compared to liquid-state reactions. A continuous layer of Ni3Sn4 IMC with curved chunky-type or more appropriately scallop-type morphology has been reported to form during solid-state reaction instead of needle-type and chunky-type grains with channels that formed in the case of liquid-state reflow [9]. Based on all of these aforementioned studies, a partial but common understanding of elemental diffusion and reaction mechanism at the electroless Ni-P/Sn-bearing solders can be made, and elaborated as follows.…”
Section: Morphology Of Intermetallic Compoundmentioning
confidence: 99%
“…In solid-state reactions, the morphology of Ni3Sn4 becomes quite different as compared to liquid-state reactions. A continuous layer of Ni3Sn4 IMC with curved chunky-type or more appropriately scallop-type morphology has been reported to form during solid-state reaction instead of needle-type and chunky-type grains with channels that formed in the case of liquid-state reflow [9]. Based on all of these aforementioned studies, a partial but common understanding of elemental diffusion and reaction mechanism at the electroless Ni-P/Sn-bearing solders can be made, and elaborated as follows.…”
Section: Morphology Of Intermetallic Compoundmentioning
confidence: 99%