Interfacial behaviour of non-aqueous solvents

New Features and Uncovered Benefits of Polycrystalline Magnetite as Reusable Catalyst in Reductive Chemical Conversion

“…Fe is referenced to 4.44 V to denote it versus standard hydrogen electrode (SHE). 49 The results suggest that ε 0…”

Chemisorption interaction of liquid electrodes of gallium and In–Ga, Cd–Ga and Tl–Ga alloys with solvents in a wide range of their donor numbers

“…It should be noted that numerous data on the edl structure on sp-metals in various solvents indicate that the M-S chemisorption interaction is minimum in the case of Hg electrode. Therefore, probably, physical effects of M-S interaction ((dv m ) phys ) r=0 make the main contribution to the (dv s ) r=0 value obtained in [49]. In this connection, in the case of Hg electrode, the contribution of chemisorption's components ((dv s ) chem ) r=0 to the (dv s ) r=0 remains unknown.…”

“…Notice that the accuracy and reliability of determination of E r=0 are higher than those for ðD M S wÞ r¼0 . In [49], on the basis of the data on the Volta potentials at the Hg/electrolyte solutions in different solvents reported in [50], it was shown that the variation in the differences of ðD Hg S wÞ r¼0 ¼ ðdv m À dv s Þ r¼0 correlates with the variation in the DN of solvent. The author [49] starts from the assumption that (dv m ) r=0 is independent of the solvent nature.…”

“…In [49], on the basis of the data on the Volta potentials at the Hg/electrolyte solutions in different solvents reported in [50], it was shown that the variation in the differences of ðD Hg S wÞ r¼0 ¼ ðdv m À dv s Þ r¼0 correlates with the variation in the DN of solvent. The author [49] starts from the assumption that (dv m ) r=0 is independent of the solvent nature. In this case, the variation in ðD Hg S wÞ r¼0 in the series of solvents reflects the variation in the (dv s ) r=0 component.…”

Effect of the metal nature on the n-butanol adsorption in the absence of the metal–water chemisorption interaction

“…The energy of the metalsolvent chemisorption interaction depends not only on the metal nature but also on the solvent nature. It increases with decreasing negative charge of the electrode and is accompanied by the solvent dipole reorientation in the EDL dense part [1,2,[24][25][26][27]. The chemisorption interaction is of donor-acceptor nature; it increases with increasing donor number of solvent.…”