In recent years, additive manufacturing technologies have become increasingly widespread with the most intensive development being direct metal deposition (DMD), alloys, and ceramic materials on a metal substrate. This study shows the possibilities of the effective formation of coatings, based on heterogeneous metal alloys (Ni-based alloy and Fe-Al bronze) deposited onto 1045 structural steel. Changes in the microhardness, the microstructure, and the tribological properties of the composite coating, depending on the laser spot speed and pitch during DMD processing, have been considered. It was revealed that if the components of the composite coating are chosen correctly, there are possible DMD conditions ensuring reliable and durable connection between them and with the substrate.