Major results from a petrographic study of porcellanites and cherts are as follows: 1) Acoustic Horizon A consists of isochronous but facies-independent lower to middle Eocene immature porcellanites. A biogenic silica source is inferred. The porous sediments are first cemented and later replaced by opal-CT, producing a dense or lepispheretype fabric. Porcellanites within the clayey environment include silicified (radiolarian) mudstones and turbidite sands rich in sponge spicules. Poorly consolidated Eocene chalks show gradual transi¬ tions to calcareous porcellanites, which contrast with the discrete nodules typical of more strongly lithified carbonates.2) Before chertification, early-diagenetic quartz occurs locally in porcellanites as replacement of foraminifer tests and latest-genera¬ tion cavity-filling cement.3) With increasing burial depth and age, radiolarians are trans¬ formed in situ from the original opal-A into opal-CT, and finally into quartz. The boundary between sediments containing siliceous fossils preserved as opal-A and as opal-CT coincides with the up¬ permost porcellanites of each site.4) The diagenetically mature Lower Cretaceous quartz cherts contain quartz-replaced lepispheres, suggesting a porcellanitic pre¬ cursor stage. This indicates an age-, temperature-, and facies-controlled maturation process from opal-A to quartz via opal-CT.