Interlayer confinement mediated oxidation of americium by sodium bismuthate and stability of its higher redox states in acidic solution

Verma, Parveen K.; Bhattacharyya, Arunasis; Mohapatra, Prasanta K.

doi:10.1039/d4dt00719k

Dalton Trans.

2024

DOI: 10.1039/d4dt00719k

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Interlayer confinement mediated oxidation of americium by sodium bismuthate and stability of its higher redox states in acidic solution

Parveen K. Verma,

Arunasis Bhattacharyya,

Prasanta K. Mohapatra

Abstract: Interlayer ion exchange assisted Am3+ oxidation to AmO22+ on NaBiO3·xH2O (x = 2–3) was seen in acidic solution. Am redox transformation also perturbing NaBiO3·xH2O (x = 2–3) lattice structure, making its dissolution easier even at low acidity.

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Interlayer confinement mediated oxidation of americium by sodium bismuthate and stability of its higher redox states in acidic solution

Abstract: Interlayer ion exchange assisted Am3+ oxidation to AmO22+ on NaBiO3·xH2O (x = 2–3) was seen in acidic solution. Am redox transformation also perturbing NaBiO3·xH2O (x = 2–3) lattice structure, making its dissolution easier even at low acidity.

Cited by 0 publications

References 49 publications

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