2007
DOI: 10.1002/anie.200702360
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Interlayer Modification of a Layered Titanate with Two Kinds of Organic Functional Units for Molecule‐Specific Adsorption

Abstract: Layered materials have widely been used as adsorbents, catalysts, catalyst supports, and hosts for functional molecular species, owing to 1) their large surface areas derived from well-defined nanostructures composed of ultrathin sheets, 2) their chemical stability, and 3) the diversity of the materials.[1] The modification of interlayer nanospaces has been conducted through ion exchange [2] and grafting.[3] Though there have been several examples in which the adsorptive characteristics of layered materials h… Show more

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Cited by 69 publications
(79 citation statements)
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“…Intercalation of organic functionalities inside LTs galleries is also reported [19][20][21]. Octadecylsilyl and phenylsilyl groups were successfully intercalated inside K 0.80 Ti 1.73 Li 0.27 O 4 through a stepwise procedure in which intermediate dodecyltrimethylammoniumexchanged K 0.80 Ti 1.73 Li 0.27 O 4 had been formed first.…”
Section: Introductionmentioning
confidence: 82%
“…Intercalation of organic functionalities inside LTs galleries is also reported [19][20][21]. Octadecylsilyl and phenylsilyl groups were successfully intercalated inside K 0.80 Ti 1.73 Li 0.27 O 4 through a stepwise procedure in which intermediate dodecyltrimethylammoniumexchanged K 0.80 Ti 1.73 Li 0.27 O 4 had been formed first.…”
Section: Introductionmentioning
confidence: 82%
“…Ogawa has reported the synthesis of alkyl and phenyl mixed groups modified layered titanate [13] or silicate [14] and their adsorption behaviors to 4-nonylphenol. The alkyl and phenyl groups are both responsible for the adsorption of the target with multiple functional groups, which is important for the moleculespecific adsorption.…”
Section: Introductionmentioning
confidence: 99%
“…These compounds have found use as fillers, 1 adsorbents for water treatment and nuclear waste cleanup, 2,3,4 functional nanosheets 5 and photocatalysts. 6 Several layered titanates have recently been shown to undergo reversible reductive intercalation of both lithium and sodium ions.…”
Section: Introductionmentioning
confidence: 99%