2020
DOI: 10.1002/ejoc.202001260
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Intermediate Products of C60 High‐Temperature Chlorination – C60Cln (n = 8, 10, 14, 20, 24)

Abstract: The products of high‐temperature (440 °C) chlorination of C60 with SbCl5 differ considerably from the products obtained at room temperature because high‐temperature allows for chlorine migration over the fullerene cage. Thus, one can expect to obtain the most favorable chlorination patterns for any C60Cln stoichiometry. We report the isolation and structural characterization of several chlorofullerenes, C2v‐C60Cl8, C1‐C60Cl10, and C1‐C60Cl14, which are intermediates to the more kinetically stable higher chlori… Show more

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Cited by 4 publications
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