Intermolecular interactions, photocatalysis and THz-TDS interrelationships for lanthanide phosphine oxide complexes based on {PW12}

Modulation on terahertz absorption properties in LnIII–[AgI(CN)2] networks

“…50 However, compared to the extensive studies for magnetic, luminescence, spectroscopic, and NLO properties for Ln(III) complexes, the lanthanide tuning effects have been rarely studied in the THz region. [48][49][50][51][52][53][54] Concurrently, silver ions (Ag(I)) compounds have appeared to be noteworthy candidates to create THz absorbing materials. Notably, the phonon spectra of AgCN compound exhibit low-frequency THz peaks at ca.…”

Facile fabrication and characterization of rare earth complexes based on Keggin-type polyoxometalate with highly efficient activity for photocatalytic degradation of MO

“…, W 6+ , Mo 6+ , V 5+ , Ta 5+ ) and oxygen atoms of metal–oxygen cluster (MO x ) polyhedrons, 15–17 have developed into molecular nanoclusters with a uniform structure and well-defined composition exhibiting a wide range of applications in catalysis, nanoscience, biology, medicine and other fields. 18,19 POMs can be deemed as analogues of semiconductor metal oxides because they are all composed of d0 transition metals and have similar electronic properties, containing a specific gap of HOMO–LUMO. 20–23 POMs have tunable composition, structure, charge and size as well as distinct photoinduced charge transfer properties, strong photooxidation–photoreduction capability, and elevated chemical and thermal stability, which are essential in photocatalysis.…”

Efficient dye degradation and THz spectra of {PMo12} based rare earth phosphine oxide complexes

“…In previous work, we have synthesized some rare earth complexes containing bisphosphonate ligands and characterized them by terahertz time-domain spectroscopy. 38–42 The THz test of the complexes provided data for the THz database and contributed to subsequent research.…”