Internal Cation Mobilities in the Molten Systems (Ag, Rb)NO<sub>3</sub> and (Ag,Cs)NO<sub>3</sub> Remeasured by the Klemm Method

Chou, Pao-Hwa; Matsuura, Haruaki; Okada, Isao

doi:10.1515/zna-1993-1209

Search citation statements

Order By: Relevance

Paper Sections

Select...

Introduction1

Citation Types

Supporting

Mentioning

Contrasting

Year Published

1997

2000

Publication Types

Select...

Article2

Relationship

Self Cite0

Independent2

Authors

Journals

Cited by 2 publications

(1 citation statement)

References 0 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Un<UAO UN,, < UAI (8) 84RI < U11 (9) whereas the ionic radius of Ag is considerably greater than that of Nat This suggests that the distances of Ag -NO; and Ag -Ag become smaller than expected owing to the high polarizability. Similarly, the AgT -Ag pair potential in AgC1 21 is compared with that of NaT -NaT in MaCI in Fig.…”

Section: Introductionmentioning

confidence: 88%

Anomalous Behavior of Internal Mobilities for Ag(I) and Tl(I) Ions in Molten Nitrates

Okada

Chou

1997

J. Electrochem. Soc.

View full text Add to dashboard Cite

The data on internal cation mobilities, it, in the molten binary nitrate systems (Ag, M)N03 and (Ti, M)N03 (M = alkali metal ion) previously obtained by us have been re-examined. In binary alkali nitrates it is known to be well expressed by an empirical equation u = {A/(Vm -17)} exp (-E/RT), where V,,, is the molar volume; while A, V6, and E are constants nearly independent of the cations with which they are mixed. It is found that in melts containing U for the M deviates negatively from this equation, and that with TF, UM deviates positively. Thus, Ag and TV both with relatively high polarizabilities, have opposite effects on UM, that is a tranquilization effect and an agitation effect, respectively. The reason has been interpreted in terms of the high polarizabilities and the difference in the sizes of Ag and TV.

show abstract

Section: Introductionmentioning

confidence: 88%

Anomalous Behavior of Internal Mobilities for Ag(I) and Tl(I) Ions in Molten Nitrates

Okada

Chou

1997

J. Electrochem. Soc.

View full text Add to dashboard Cite

show abstract

Rotational and vibrational relaxation of the NO₃^-ion in molten binary systems (M,Ag)NO₃(M = Li, Na and K) by Raman spectroscopy

Chou

Okada

2000

Molecular Physics

View full text Add to dashboard Cite

Internal Cation Mobilities in the Molten Systems (Ag, Rb)NO₃ and (Ag,Cs)NO₃ Remeasured by the Klemm Method

Abstract: Internal mobility ratios in the molten binary systems (Ag,Rb)NO

Cited by 2 publications

References 0 publications

Anomalous Behavior of Internal Mobilities for Ag(I) and Tl(I) Ions in Molten Nitrates

Anomalous Behavior of Internal Mobilities for Ag(I) and Tl(I) Ions in Molten Nitrates

Rotational and vibrational relaxation of the NO₃^-ion in molten binary systems (M,Ag)NO₃(M = Li, Na and K) by Raman spectroscopy

Contact Info

Product

Resources

About

Internal Cation Mobilities in the Molten Systems (Ag, Rb)NO3 and (Ag,Cs)NO3 Remeasured by the Klemm Method

Abstract: Internal mobility ratios in the molten binary systems (Ag,Rb)NO

Cited by 2 publications

References 0 publications

Anomalous Behavior of Internal Mobilities for Ag(I) and Tl(I) Ions in Molten Nitrates

Anomalous Behavior of Internal Mobilities for Ag(I) and Tl(I) Ions in Molten Nitrates

Rotational and vibrational relaxation of the NO3-ion in molten binary systems (M,Ag)NO3(M = Li, Na and K) by Raman spectroscopy

Contact Info

Product

Resources

About

Internal Cation Mobilities in the Molten Systems (Ag, Rb)NO₃ and (Ag,Cs)NO₃ Remeasured by the Klemm Method

Rotational and vibrational relaxation of the NO₃^-ion in molten binary systems (M,Ag)NO₃(M = Li, Na and K) by Raman spectroscopy