2005
DOI: 10.1016/j.cemconres.2004.06.030
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Internal deterioration of concrete by the oxidation of pyrrhotitic aggregates

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Cited by 50 publications
(53 citation statements)
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“…El uso de polisacáridos en cemento tiene influencia en la hidratación de las pasta de cemento, ya que actúan como agentes retardadores y no permiten la libre formación del hidróxido de calcio y del silicato hidratado de calcio (8 nopal cactus mucilage. The crystalline products observed in both cases are in agreement with those reported in the literature on cement hydration (20,21). Figure 7 shows the diffractograms for cement pastes with w/c and m/c ratio= 0.45 at ages of 3 and 28 days; the crystalline products induced by cement hydration as well as calcium carbonate produced by the cement paste carbonation, are identified.…”
Section: X-ray Diffractionsupporting
confidence: 78%
See 1 more Smart Citation
“…El uso de polisacáridos en cemento tiene influencia en la hidratación de las pasta de cemento, ya que actúan como agentes retardadores y no permiten la libre formación del hidróxido de calcio y del silicato hidratado de calcio (8 nopal cactus mucilage. The crystalline products observed in both cases are in agreement with those reported in the literature on cement hydration (20,21). Figure 7 shows the diffractograms for cement pastes with w/c and m/c ratio= 0.45 at ages of 3 and 28 days; the crystalline products induced by cement hydration as well as calcium carbonate produced by the cement paste carbonation, are identified.…”
Section: X-ray Diffractionsupporting
confidence: 78%
“…As can be observed in these diffractograms, there is ettringite, calcium hydroxide, calcium carbonate, as well as consumption of C 2 S and C 3 S. Notice that in case of the paste containing nopal cactus mucilage (Figures 6c and 6d), the reduction of C 3 S y C 2 S is less than in the paste containing only water (Figures 6a and 6b), indicating a slow cement hydration in the presence of del mucílago de nopal. Los productos cristalinos observados en ambos casos son congruentes con los reportados en la literatura sobre hidratación de cemento (20,21).…”
Section: X-ray Diffractionmentioning
confidence: 86%
“…Ettringite is stable at lower pH than portlandite, i.e., between 12.5 and 10 [21]. According to Terai et al [22] it forms above a Ca/Al ratio of 1.5, and above a pH of 9.86.…”
Section: Influence Of Aggregatesmentioning
confidence: 99%
“…Esse processo pode gerar produtos como íons sulfato, que em contato com os produtos da hidratação do cimento como Ca(OH)2 e os produtos do cimento anidro como o C3A (aluminato de cálcio) formam compostos mais volumosos, causando os efeitos deletérios nas estruturas de concreto [3][4][5][6][7][8][9][10]. Ainda, segundo os autores, é possível elencar os principais fatores que aceleram o processo de alteração dos sulfetos contidos nos agregados, sendo eles: a concentração elevada de oxigênio; a presença de umidade; a superfície específica; os altos teores de ferro e os valores de pH acima de 10 [3].…”
Section: Introductionunclassified