Research on land grabs has identified the Gulf Arab states as major actors in the acquisition of agricultural land. However the role of these investments in the economies of the Gulf remains underexplored in the scholarly literature. In response, I propose that these projects are part of commodity chains that are articulated to the agribusiness industry in the Gulf states. I argue that they are extractive zones; enclaves created through articulation to the investor states, and disarticulation from their host society. With this considered, the commodity chains that link these projects with the Gulf economies transfer surplus value in the form of labour time, but also biophysical matter such as water, energy, and soil nutrients. This focus on the appropriation of nature allows a better understanding of these schemes and their role in the Gulf’s economic growth. As will be demonstrated, the cycle of exhaustion of water impells the location of these land grabs, and this context connects them with the history of domestic projects. This article uses a framework that integrates theory on the spatial contestations of commodity chains with work on political ecology, and by doing so it contributes to a growing body of work that examines the relationship between networks of commodity production and nature.