High-performance warm-white light-emitting diode (LED) devices are in great demand toward green and comfortable solid-state lighting. Herein, we report a creative green-emission CaY 2 HfGa(AlO 4 ) 3 :Ce 3+ phosphor. CaY 2 HfGa(AlO 4 ) 3 :Ce 3+ compounds with different cerium ion doping contents have been successfully prepared through a conventional high-temperature solid-state method, and their phase and crystal structure have been revealed via the powder X-ray diffraction and Rietveld refinement. Impressively, the CaY 2 HfGa(AlO 4 ) 3 :Ce 3+ phosphors exhibit a broad-band excitation, which well covers the wavelength region from the 300 to 500 nm, corresponding to the commercial blueemitting LED chip. Upon 450 nm excitation, the optimal CaY 2 HfGa(AlO 4 ) 3 :2%Ce 3+ sample shows an intense broad-band green emission (the corresponding testing spectral range: 460− 750 nm) with a strongest peak about 534 nm. In addition, the CaY 2 HfGa(AlO 4 ) 3 :2%Ce 3+ sample possesses a broad full width at halfmaximum equal to 120 nm; moreover, its CIE chromaticity coordinate and the internal quantum efficiency are determined to be (0.3541, 0.5427) and 72.8%, respectively. A high-quality warm-white LED has been fabricated through incorporating our CaY 2 HfGa(AlO 4 ) 3 :2%Ce 3+ green phosphors and commercial red phosphors with the 450 nm blue LED chip. When upon the 20 mA bias driving current, the LED device demonstrates a bright warm-white light emission, which possesses a satisfactory color rendering index of 91, a low correlated color temperature of 4080 K, as well as a good luminous efficacy of 85.14 lm W −1 . The creative greenemitting CaY 2 HfGa(AlO 4 ) 3 :Ce 3+ garnet phosphor has a bright application prospect toward high-quality warm-white LED lighting.