On the basis of concept, characteristics and related work of collaborative learning, this paper proposes an intelligent web collaborative learning system prototype based on multi-agent technology. At first, the paper introduces a collaborative learning framework which supporting group learning and illustrates the whole learning process. Secondly, the paper presents some key issues to implementation of the virtual learning environment, such as intelligent grouping, automatic question answering, knowledge management, and opinion mining. Preliminary learning practice shows that it is a practical and efficient way.