Interpretation of dissolution rates by the reaction fractal dimensions

Momonaga, Masashi; Stávek, Jiřı́; Ulrich, Joachim

doi:10.1016/0022-0248(96)00108-x

Cited by 6 publications

(1 citation statement)

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“…In both cases, the calculated and theoretical D R values were found to be identical. Momonaga et al (1996) suggested that the reactive fractal dimension varies with dissolution behavior and carried the information about the mechanism of the dissolution process. The first group of particles were Smoluchowskian particles, the volume of which was composed of several organized agglomerated growth units.…”

Section: Reactive Fractalsmentioning

confidence: 99%

Fractal analysis in particle dissolution: a review

Bao

Long

et al. 2014

Reviews in Chemical Engineering

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Abstract:Fractal is a geometric language to describe the objects, the systems, and the phenomenon spatially and temporally. This paper reviews the literature on fractal models developed to describe the dissolution of particles. Dissolution, the process by which a solid forms a homogeneous mixture with a solution, is the behavior of a population of particles rather than a single one in most of the cases. The fractal models developed for the particle population are reviewed on the basis of two key particle surface properties, namely, the surface fractal nature and the chemical reactivity of particle surfaces. In terms of the surface fractal nature, fractals have been used to describe the change in the superficial roughness of particles, surface area-particle size relation, and particle size distribution (PSD). In terms of the reactive fractal dimensions, the models that describe the dissolution process have been developed to obtain the empirical noninteger exponent, the reactive fractal dimension that can dictate the chemical reactivity of a solid surface. The comparison between the surface fractal dimension and the reactive fractal dimension provides the dissolution mechanisms in many aspects of surface morphology. Further research is necessary to modify the current models to coincide with the real industrial processes and production and to develop the specific models for a better understanding of many processes involving the dissolution of particles encountered in many areas, including pharmaceutical and chemical applications and hydrometallurgy.

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Section: Reactive Fractalsmentioning

confidence: 99%