Interpretation of paleodepositional environment using biomarkers and carbon isotope (δ¹³C) in Talang Akar Formation, South Sumatra Basin, Indonesia

Abstract

Talang Akar Formation is a proven hydrocarbon source rock in South Sumatra basin. The formation contains dominant shale at the top, with some sandstone interbeds. This study uses 3 crude oil sample and 10 well-cutting obtained from two well (SMT-1 & SMT-2) in Prabumulih oil field. We used biomarkers and carbon isotopes (δ13C) data to determine the paleodepositional environment of Talang Akar Formation. The biomarkers data were obtained from gas chromatography (GC) and gas chromatography-mass spectrometry (GC-MS) analysis of normal alkanes, isoprenoids, triterpene, and steranes. Carbon isotopes (δ13C) include saturated and aromatic fractions. The pristine (Pr) to phytane (Ph) ratio is a good indicator of the depositional environment. Higher values of Pr/Ph ratio i.e. ≥3.0 indicate oxidizing conditions i.e. terrestrial while lower values in the range of 1.0-3.0 suggests siliciclastic-dominated marine conditions. However, very low values i.e. ≤ 1.0 indicate reducing conditions or fresh and brackish water conditions. The results in this research show that Pr/Ph ratios range from 7.90-16.66, characteristic of high wax crude oils, primarily originated in fluviatile and deltaic environment containing a significant amount of terrestrial organic matter. Similarly, the resultant ratios of Pr/n-C17 and Ph/n-C18 in SMT-1 and SMT-2 wells range from 0.91-10.72 and 0.11-1.29 respectively, which reflect that most of kerogen was derived from humic source and tend towards an oxidative environment of deposition. Cross-plot of carbon-13 isotopes (δ13C) shows saturated versus aromatic fraction. The resultant plot indicate a deltaic to marginal marine environment for SMT-2 well and a more marine environment for SMT-1 well. The oil/source rock correlation analysis using biomarker data shows that the oils in Prabumulih field is correlated with the oils in source rock of Talang Akar Formation. This study concludes that the source rock contains abundant humic organic matter that was deposited in a transitional (Fluvio-deltaic) to marginal marine environment under oxic conditions.

Chemometrics, health risk assessment and probable sources of soluble total petroleum hydrocarbons in atmospheric rainwater, Rivers State, Nigeria

“…It is the ratio of the abundance of pristane to phytane for redox conditions in the aquatic environment, based on the assumption that pristane is from oxygenated (aerobic) source degradation of planktons, while phytane is from reduction (anaerobic) source degradation of planktons by microbes. As such, Pristane/phytane ratio below unity (1) indicates oxic condition (pyrogenic source), while greater than 1 indicates anoxic (biogenic source) 31 .…”