In this study, the electron density of plasma discharge has been obtained using the innovative combination of a basic theoretical relation and measured current-voltage characteristics of a uniform glow discharge of a spark array TEA-CO 2 laser. The maximum values of electron densities have been obtained as 1.93 × 10 13 , 1.95 × 10 13 and 2.15 × 10 13 cm −3 , respectively, for charging voltage of discharges at 18, 20 and 22 kV. The drift velocity of electrons has been obtained in the different conditions versus the reduced electric field (E/N) and gas mixtures in the discharge tube. Furthermore, the efficiency in energy conversion and the behavior of electrical energy density versus reduced electric field has been studied.