Dalton Trans.
 2024
DOI: 10.1039/d4dt00089g
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Intramolecular dearomative 1,4-addition of silyl and germyl radicals to a phenyl moiety

Felix Krämer,
Jonas O. Wenzel,
Israel Fernández
et al.

Abstract: Herein, we present that the radicals [Ph3PC(Me)EMes2]• (2Si and 2Ge) can be generated from the α silylated and α-germylated phosphorus ylides Ph3PC(Me)E(Cl)Mes2 (1Si and 1Ge) through one-electron reduction with Jones’...

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