Using a tilted field geometry, the effect of an in-plane magnetic field on the even denominator ν = 5 2 fractional quantum Hall state is studied. The energy gap of the ν = 5 2 state is found to collapse linearly with the in-plane magnetic field above ∼ 0.5T. In contrast, a strong enhancement of the gap is observed for the ν = 7 3 state. The radically distinct tilted-field behaviour between the two states is discussed in terms of Zeeman and magneto-orbital coupling within the context of the proposed Moore-Read Pfaffian wavefunction for the The incompressible even-denominator fractional quantum Hall effect (FQHE) at filling factor ν = 5 2 [1] remains one of the most exotic phenomena ever discovered in condensed matter physics. Of the ∼100 FQH states observed in high-mobility two-dimensional electron gas (2DEG) structures, the 5 2 FQH state continues to represent the only violation of the odd-denominator rule. Aside from the fundamental questions this even-denominator FQH state raises concerning our understanding of strongly correlated electron behaviour, the 5 2 state has received particular attention because of its possible description by the Moore-Read Pfaffian wave function [2], which exhibits non-abelian quantum statistics. This potential non-abelian property makes the 5 2 FQHE a strong candidate for the realization of fault-tolerant topological quantum computation [3]. Recent measurements of the e * = e/4 quasi-particle charge [4], as well as the tunneling spectra [5], are fully consistent with a Moore-Read Pfaffian wavefunction (or its particle-hole conjugate, the so-called anti-Pfaffian [6,7]). However, an unequivocal experimental proof is still lacking, in part due to other possible candidate paired-states, such as the (abelian) Halperin (3,3,1) state, which could in principle be realized at ν = Key features of the Moore-Read Pfaffian that distinguish it from other possible wavefunctions include its fully spin-polarized electron polarization [10,11,12], as well as the non-zero angular momentum of its p x + ıp y pairing, very similar to the A 1 -phase of superfluid 3 He. In this Letter, we investigate the 5 2 FQH spin polarization by measuring the activation energy gap of the 5 2 (and particle-hole conjugate 7 2 ) and neighbouring 7 3 state in a tilted field geometry where, in addition to the perpendicular field (B ⊥ ), a parallel field (B ) is applied in the plane of the 2DEG. Two important aspects distinguish our work from previous tilted field experiments in the second Landau level (SLL) [13,14,15,16,17]. First, we examine a relatively strong 5 2 -state occurring at lower magnetic field than previously observed (owing to our low density sample [18]) in the non-perturbative Landau level coupling regime where the Coulomb interaction energy is greater than the Landau level separation.Secondly, we study the FQH energy gap in a sample with a relatively wide 2D quantum well so that under tilt the magnetic length associated with B becomes of order or smaller than the well width, allowing us to study the effect ...