During recent years the counterparty risk subject has received a growing attention because of the so called Basel Accord. In particular the Basel III Accord asks the banks to fulfill finer conditions concerning counterparty credit exposures arising from banks' derivatives, securities financing transactions, default and downgrade risks characterizing the Over The Counter (OTC) derivatives market, etc. Consequently the development of effective and more accurate measures of risk have been pushed, particularly focusing on the estimate of the future fair value of derivatives with respect to prescribed time horizon and fixed grid of time buckets . Standard methods used to treat the latter scenario are mainly based on ad hoc implementations of the classic Monte Carlo (MC) approach, which is characterized by a high computational time, strongly dependent on the number of considered assets. This is why many financial players moved to more enhanced Technologies, e.g., grid computing and Graphics Processing Units (GPUs) capabilities. In this paper we show how to implement the quantization technique, in order to accurately estimate both pricing and volatility values. Our approach is tested to produce effective results for the counterparty risk evaluation, with a big improvement concerning required time to run when compared to MC approach.